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"Advent calendar #6: The dissolved Nobel Prizes"

5 Comments -

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Blogger Phil Warnell said...

Hi Bee,

Thanks as it being yet another nice story to which I wasn't privy before. Then again despite what de Hevesy did the information regarding the two medals is still to be found in the universe; that is unless it fell into a black hole of course. However rumor has it that there are those that would disagree :-)

Best,

Phil

7:04 AM, December 06, 2011

Blogger Rhys said...

That's a wonderful story (although set against the rather horrendous background of the Nazis' spread across Europe). How remarkable for the medals to ultimately be cast again from the same gold!

8:13 AM, December 06, 2011

Blogger Alyssa said...

What an amazing story!

9:49 AM, December 06, 2011

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11:02 AM, December 06, 2011

Blogger Uncle Al said...

Dissolving gold requires a coordinating ligand plus an oxidant. Saltwater (chloride) plus air will do it (slowly), as will cyanide in water plus air (solution heap mining), producing soluble [AuCl2]- and [Au(CN)2]- respectively, Au(I).

Aqua regia, 82 vol-% 15M HCl plus 18 vol-% 12M HNO3 then aged about 15 minutes (keep covered, fumes!), goes through gold like a buzz saw. Huge chloride concentration is abetted by powerful oxidants NOCl and some free chlorine to obtain [AuCl4]-, Au(III).

Recover the gold with a mild reductant... but NEVER with ammonia ("explosive gold").

11:11 AM, December 06, 2011

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